Wednesday, May 30, 2012
Reactions of Butylated Hydroxytoluene (BHT)
Butylated hydroxytoluene (BHT), also known as butylhydroxytoluene, is a lipophilic (fat-soluble) organic compound, chemically a derivative of phenol, that is useful for its antioxidant properties. European and U.S. regulations allow small percentages to be used as a food additive, but that is not without controversy as there are claimed links to child hyperactivity as well as to cancer. Conversely, BHT is advocated as a diet supplement and antiviral useful against herpes family viruses. While there may be some dispute in BHT's use in the human diet, the chemical is widely used in industry wherever oxidation in fluids (e.g. fuel, oil) and other materials must be treated, and free radicals must be kept in-check.
The species behaves as a synthetic analogue of vitamin E, primarily acting as a terminating agent that suppresses autoxidation, a process whereby unsaturated (usually) organic compounds are attacked by atmospheric oxygen. BHT stops this autocatalytic reaction by converting peroxy radicals to hydroperoxides. It affects this function by donating a hydrogen atom:
RO2. + ArOH → ROOH + ArO. RO2. + ArO. → nonradical products
where R is alkyl or aryl, and where ArOH is BHT or related phenolic antioxidants. Each BHT consumes two peroxy radicals.
Read More: Butylated hydroxytoluene (BHT) suppliers
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